29 July 1892
26 July 1969
|Institutions||BASF, University of Mainz, TH Darmstadt|
University of Jena,
University of Munich
|Known for||chemistry of acetylene|
- Education and career 1
- Acetylene chemistry 2
- Reppe chemistry 3
- Post-war 4
- Legacy 5
- Publications 6
- References 7
Education and career
In 1921, Reppe worked for BASF's main laboratory. From 1923, he worked on the catalytic dehydration of formamide to prussic acid in the indigo laboratory, developing this procedure for industrial use. In 1924, he left research for 10 years, only resuming it in 1934.
Reppe began his interest in acetylene in 1928. Acetylene is a gas which can take part in many chemical reactions. However, it is explosive and accidents often occurred. Because of this danger, small quantities of acetylene were used at a time, and always without high pressures. In fact, it was forbidden to compress acetylene over 1.5 bar at BASF.
Reactions at such low pressures did not correspond at all to the traditions at BASF, and one could not expect any useful process engineering results. Reppe commented in 1949 retrospectively: "therefore the necessity resulted to break with all delivered opinions and to study first of all the acetylene decay with consideration of the most diverse test conditions of reason on, in order to determine suitable safety precautions, one safe working also in the industrial yardstick made possible." To work with acetylene safely, Reppe designed special test tubes, the so-called "Reppe glasses" — stainless steel spheres with screw-type cap, which permitted high pressure experiments. The efforts ended finally with a large number of interrelated reactions, known as Reppe chemistry.
- The vinylization according to the equation:
- Preparing ethynyldiols from aldehydes according to the equation:
- Reactions with carbon monoxide:
- The cyclic polymerization or cyclo-oligomerization of acetylene to cyclooctatetraene, which is one of the most important applications of template reactions. The reaction occurs at a nickel(II) centre, where it is supposed that four acetylene molecules occupy four sites around the metal, and react simultaneously to give the product.
If a competing ligand such as triphenylphosphine is present in sufficient proportion to occupy one coordination site, then room is left for only three acetylene molecules, and these come together to form Benzene
Products from these four reaction types proved to be versatile intermediates in the syntheses of lacquers, adhesives, foam materials, textile fibers, and pharmaceuticals could now be produced.
After the Second World War, Reppe led the research of BASF from 1949 up to his retirement in 1957. From 1952 to 1966, he also sat on the supervisory board. He was also a professor at the University of Mainz and TH Darmstadt from 1951 and 1952 respectively. Together with Otto Bayer and Karl Ziegler he received the Werner von Siemens Ring in 1960 for expanding the scientific knowledge on and for the technical development of new synthetic high-molecular materials.
Most of the industrial processes that were developed by Reppe and coworkers have been superseded, largely because the chemical industry has shifted from coal as feedstock to oil. Alkenes from thermal cracking are readily available, but acetylene is not.
Together with his contemporaries organometallic chemistry and its close connection to industry.
- Neue Entwicklungen auf dem Gebiet der Chemie des Acetylen und Kohlenoxyds (New developments in the area of the chemistry acetylene and carbon monoxide). Springer Berlin, Göttingen, Heidelberg. 1949. 184 pages.
- Reppe, W.; Schlichting, O.; Meister, H. (1948). "Cyclisierende Polymerisation von Acetylen. II Über die Kohlenwasserstoffe C10H10, C12H12 und Azulen" [Cyclizing reactions of Acetylene: 2nd About the hydrocarbons C10H10, C12H12 and Azulene]. Justus Liebigs Annalen der Chemie (in German) 560: 93.
- "Cyclisierende Polymerisation von Acetylen. III Benzol, Benzolderivate und hydroaromatische Verbindungen" [Cyclizing reactions of Acetylene. 3rd Benzene, derivates of Benzene and hydroaromatic compounds]. Justus Liebigs Annalen der Chemie (in German) 560: 104–116. 1948.